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For the edges you can pick up the non-toxic CA glue from a hobby shop. Just apply a thin layer of it and allow it to dry. Avoid doing it under florescent light as it will turn white.
You really don't need to clear it afterwards unless you want the edges of it to be shiny. You only really need to worry about protecting it if it is going to be exposed to a lot of UV rays, like the sunroof of a car or hood for example. The resin that is used to actually make the sheet stiff is really all the protection it needs.
I probably still would for cosmetic reasons, just because he's using it for a pick guard on a guitar, and probably wants it to look nice and shiny.
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